Arena skills override the Normal Skills, so in the example of Selina's Knockback skill and her Backstab Arena Skill, once she is deployed in the Guild War event, her Backstab Arena Skill will only proc and her Knockback skill with be ignored.
The same goes for Aksana's Iron Wall. Her Slow skill will never proc during a Guild War or Battle Arena event.
During normal quests and certain other events, Aksana's Slow skill and Selina's Knockback skill will proc, while their Arena Skills will be disabled.